杨桃叶的化学成分研究
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国家重点基础研究发展计划(973计划)(2013CB127106);广东省应用型科技研发专项(2016B020239004)资助


Chemical Constituents from the Leaves of Averrhoa carambola
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    摘要:

    为阐明酢浆草科植物杨桃(Averrhoa carambola)的化学成分,运用有机溶剂提取、萃取及多种色谱分离技术,从其叶中分离得到11个化合物。经光波谱分析,分别鉴定为苯基β-d-葡萄糖苷(1)、3,4,5-三甲氧基苯基β-d-葡萄糖苷(2)、苄基β-d-葡萄糖苷(3)、2-苯乙基芸香糖苷(4)、1-O-(3,5-二甲氧基-4-羟基苯甲酰)-β-d-葡萄糖(5)、5-羟基麦芽酚(6)、麦芽酚苷(7)、麦芽酚3-O-[6-O-(3-羟基-3-甲基-5-丁基戊二酰)]-β-d-葡萄糖苷(8)、乙基β-d-呋喃果糖苷(9)、丁基β-d-呋喃果糖苷(10)和鲨烯(11)。化合物8是1个新的人工产物,除化合物23外均为首次从杨桃属植物中得到。部分化合物与杨桃叶的抗炎、抗氧化和抗肿瘤作用相关。

    Abstract:

    To clarify the chemical constituents in the leaves of Averrhoa carambola (Oxalidaceae), eleven compounds were isolated by means of organic solvent extraction and fractionation as well as diverse chromato-graphic separation techniques. On the basis of spectroscopic data, their structures were identified as phenyl β-d-glucoside (1), 3,4,5-trimethoxyphenyl β-d-glucoside (2), benzyl β-d-glucoside (3), 2-phenethyl rutinoside (4), 1-O-(3,5-dimethoxy-4-hydroxybenzoyl)-β-d-glucose (5), 5-hydroxymaltol (6), maltol β-d-glucoside (7), maltol 3-O-[6-O-(3-hydroxy-3-methyl-5-butylglutaroyl)]-β-d-glucoside (8), ethyl β-d-fructofuranoside (9), butyl β-d-fructofuranoside (10), and squalene (11), respectively. Compound 8 was a new artifact, and the others excluding 2 and 3 were obtained from the genus Averrhoa for the first time. Some compounds were related to the anti-inflammatory, antioxidant, and anti-tumor effects of the leaves.

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杨月,谢海辉.杨桃叶的化学成分研究[J].热带亚热带植物学报,2021,29(1):105~111

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  • 收稿日期:2020-05-13
  • 最后修改日期:2020-06-11
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  • 在线发布日期: 2021-01-19
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