木麻黄根乙酸乙酯部位化学成分研究
作者:
基金项目:

国家自然科学基金项目(31970376);国家重点研发项目(2021YFC3100401)资助


Chemical Constituents of Ethyl Acetate Extract of Casuarina equisetifolia Roots
Author:
  • GAO Ruanling

    GAO Ruanling

    School of Pharmacy, Anhui University of Chinese Medicine, Anhui Province Key Laboratory of Research & Development of Chinese Medicine, Hefei 230012, China;Key Laboratory of South China Agricultural Plant Molecular Analysis and Genetic Improvement & Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China
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  • LUO Yucai

    LUO Yucai

    Key Laboratory of South China Agricultural Plant Molecular Analysis and Genetic Improvement & Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China;South China National Botanical Garden, Guangzhou 510650, China
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  • MA Yongyi

    MA Yongyi

    Key Laboratory of South China Agricultural Plant Molecular Analysis and Genetic Improvement & Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China;South China National Botanical Garden, Guangzhou 510650, China
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  • WANG Guokai

    WANG Guokai

    School of Pharmacy, Anhui University of Chinese Medicine, Anhui Province Key Laboratory of Research & Development of Chinese Medicine, Hefei 230012, China
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  • ZHOU Zhongyu

    ZHOU Zhongyu

    School of Pharmacy, Anhui University of Chinese Medicine, Anhui Province Key Laboratory of Research & Development of Chinese Medicine, Hefei 230012, China;Key Laboratory of South China Agricultural Plant Molecular Analysis and Genetic Improvement & Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China;South China National Botanical Garden, Guangzhou 510650, China
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  • 摘要
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    摘要:

    为阐明木麻黄(Casuarina equisetifolia)的化学成分,采用有机溶剂提取、萃取及多种分离技术,从其根中分离得到14个化合物。经光波谱分析,其结构分别鉴定为5-hydroxy-3-methoxyphenyl-6-O-syringoyl-β-d-glucopyranoside (1),高良姜苷A (2),heterophylloside C (3)、6'-O-vanilloylisotachioside (4)、3,4,5-trimethoxyphenyl-6-O-syringoyl-β-d-glucopyranoside (5)、香草醛(6)、丁香醛(7)、3,4-二羟基苯甲醛(8)、齐墩果酸(9)、桦木酸(10)、胡萝卜苷(11)、胡萝卜苷亚油酸酯(12)、(±)-lyoniresinol 2-O-a-rhamnoside (13)和(-)-9-acetyl-isolariciresinol 9'-O-a-l-rhamnopyranoside (14),其中化合物14为新的木脂素。

    Abstract:

    To clarify the chemical constituents in Casuarina equisetifolia, fourteen compounds were isolated by organic solvent extraction, fractionation, and a variety of chromatographic separation techniques. Based on spectroscopic data, their structures were identified as 5-hydroxy-3-methoxyphenyl-6-O-syringoyl-β-d-glucopy-ranoside (1), alpinoside A (2), heterophylloside C (3), 6''-O-vanilloylisotachioside (4), 3,4,5-trimethoxyphenyl-6-O-syringoyl-β-d-glucopyranoside (5), vanillin (6), syringaldehyde (7), 3,4-dihydroxybenzaldehyde (8), oleanolic acid (9), betulinic acid (10), β-sitosterol glucoside (11), daucosterol-6'-linoleate (12), (±)-lyoniresinol 2-O-a-rham-noside (13), and (-)-9-acetyl-isolariciresinol 9'-O-a-l-rhamnopyranoside (14). Among them, compound 14 is a new lignan derivative.

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高阮玲,罗喻才,马咏仪,王国凯,周忠玉.木麻黄根乙酸乙酯部位化学成分研究[J].热带亚热带植物学报,2023,31(2):289~294

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  • 收稿日期:2022-11-10
  • 最后修改日期:2022-12-30
  • 在线发布日期: 2023-03-31
  • 出版日期: 2023-03-20
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