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升振山姜茎的黄酮类成分
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广州市产学研协同创新重大专项（201604020048）；中国科学院植物资源保护与可持续利用重点实验室基金项目（201217ZS）；广东省省级科技计划项目（2013B091500076）资助


Flavonoids from the Stems of Alpinia hainanensis ‘Shengzhen’
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    摘要:

    为了解升振山姜（Alpinia hainanensis’Shengzhen‘）的化学成分，采用柱色谱技术从其茎中分离得到10个黄酮类化合物。经波谱分析，分别鉴定为（-）-乔松素（1）、（±）-山姜素（2）、（±）-7，4'-二羟基-5-甲氧基二氢黄酮（3）、4'，6'-二羟基-2'-甲氧基二氢查尔酮（4）、小豆蔻明（5）、蜡菊亭（6）、（+）-儿茶素（7）、（-）-表儿茶素（8）、原花青素A1（9）、原花青素A6（10）。体外活性测试表明，化合物1、3、5、7~10具有显著的ABTS自由基清除活性，化合物7~10具有显著的DPPH自由基清除活性。

    Abstract:

    To understand the chemical constituents of Alpinia hainanensis ‘Shengzhen’, ten flavonoids were isolated from its stems by chromatographic techniques. On the basis of spectral data, they were identified as (-)-pinocembrin (1), (±)-alpinetin (2), (±)-7,4'-dihydroxy-5-methoxy-dihydroflavonol (3), uvangoletin (4), cardamonin (5), helichrysetin (6), (+)-catechin (7), (-)-epicatechin (8), proanthocyanidin A1 (9), and proanthocyanidin A6 (10). The compounds 1, 3, 5, 7-10 exhibited remarkable ABTS radical scavenging activities and compounds 7-10 displayed significant DPPH radical scavenging activities.

    参考文献
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刘友花,林立东,叶育石,徐良雄,魏孝义.升振山姜茎的黄酮类成分[J].热带亚热带植物学报,2017,25(5):517~522

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  • 收稿日期:2017-03-02
  • 最后修改日期:2017-04-18
  • 在线发布日期: 2017-09-12
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